Isolation and structural characterization of the elusive 1:1 adduct of hydrazine and carbon dioxide.
نویسندگان
چکیده
A solid hydrazine was isolated as a crystalline powder by reacting aqueous hydrazine with supercritical CO(2). Its structure determined by single crystal X-ray diffraction shows a zwitterionic form of NH(3)(+)NHCO(2)(-). The solid hydrazine is remarkably stable but is as reactive as liquid hydrazine even in the absence of solvents.
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عنوان ژورنال:
- Chemical communications
دوره 47 40 شماره
صفحات -
تاریخ انتشار 2011